氧代丙二腈

氧代丙二腈
别名	碳酰腈; 羰基氰化物
识别
CAS号	1115-12-4
SMILES	N#CC(=O)C#N;
性质
化学式	C3N2O
摩尔质量	80.04 g·mol−1
溶解性（水）	可溶于乙醚
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氧代丙二腈是一种有机化合物，化学式为C₃N₂O。它可由四氰基环氧乙烷和甲硫醚反应制得。^[1]它可以和六氟锑酸银在二氧化硫中于低温反应，得到含阳离子框架的[Ag{NCC(O)CN}₂]_n[SbF₆]_n。^[2]它和乙烯酮反应，可以得到β,β-二氰基丙内酯。^[3]它可用于氰甲酸酯的合成。^[1]

参考文献[编辑]

^ ^1.0 ^1.1 Rondla, Naveen R.; Levi, Samuel M.; Ryss, Jonathan M.; Vanden Berg, Rachel A.; Douglas, Christopher J. Palladium-Catalyzed C−CN Activation for Intramolecular Cyanoesterification of Alkynes. Organic Letters (American Chemical Society (ACS)). 2011-03-21, 13 (8): 1940–1943. ISSN 1523-7060. doi:10.1021/ol200274h.
^ Decken, Andreas; Knapp, Carsten; Passmore, Jack. [Ag{NCC(O)CN}2]n [SbF6]n, the first metal complex of carbonyl cyanide. Journal of Chemical Crystallography (Springer Science and Business Media LLC). 2005, 35 (9): 697–700. ISSN 1074-1542. doi:10.1007/s10870-005-3618-1.
^ Hyatt, John A.; Raynolds, Peter W., Ketene Cycloadditions, Wiley, 1994-06-10, ISBN 978-0-471-26418-7, doi:10.1002/0471264180.or045.02

[Rondla-1] 1.0 ^1.1 Rondla, Naveen R.; Levi, Samuel M.; Ryss, Jonathan M.; Vanden Berg, Rachel A.; Douglas, Christopher J. Palladium-Catalyzed C−CN Activation for Intramolecular Cyanoesterification of Alkynes. Organic Letters (American Chemical Society (ACS)). 2011-03-21, 13 (8): 1940–1943. ISSN 1523-7060. doi:10.1021/ol200274h.

[2] Decken, Andreas; Knapp, Carsten; Passmore, Jack. [Ag{NCC(O)CN}2]n [SbF6]n, the first metal complex of carbonyl cyanide. Journal of Chemical Crystallography (Springer Science and Business Media LLC). 2005, 35 (9): 697–700. ISSN 1074-1542. doi:10.1007/s10870-005-3618-1.

[3] Hyatt, John A.; Raynolds, Peter W., Ketene Cycloadditions, Wiley, 1994-06-10, ISBN 978-0-471-26418-7, doi:10.1002/0471264180.or045.02

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