甲磺酸鎳是鎳的甲磺酸鹽，化學式為Ni(CH3SO3)2。它可由一氧化鎳（或鹼式碳酸鎳[1]）和甲磺酸在水溶液中反應得到，過濾去過量的氧化鎳後，從溶液中可以結晶出六水合物[Ni(H2O)6](CH3SO3)2。[2]它和2,2'-聯吡啶、一氧化碳在四丁基四氟硼酸銨的存在下於DMF中發生電化學還原（電流0.2 A）反應，可以得到Ni(CO)2bpy。[1]它在483 °C分解，產物為一氧化鎳。[3]
參考文獻[編輯]
- ^ 1.0 1.1 1.2 M. Oçafrain, M. Devaud, J.Y. Nédelec, M. Troupel. Electrochemical generation of a nickel–carbonyl complex, catalyst for the electroreductive coupling of organic halides and carbon monoxide into ketones. Journal of Organometallic Chemistry. 1998-06, 560 (1-2): 103–107 [2021-12-10]. doi:10.1016/S0022-328X(98)00515-4. （原始內容存檔於2018-06-16） （英語）.
- ^ 2.0 2.1 Sniekers, Jeroen; Verguts, Ken; Brooks, Neil R.; Schaltin, Stijn; Phan, Thanh Hai; Trung Huynh, Thi Mien; Van Meervelt, Luc; De Feyter, Steven; Seo, Jin Won; Fransaer, Jan; Binnemans, Koen. Liquid Nickel Salts: Synthesis, Crystal Structure Determination, and Electrochemical Synthesis of Nickel Nanoparticles. Chemistry - A European Journal (Wiley). 2015-12-08, 22 (3): 1010–1020. ISSN 0947-6539. doi:10.1002/chem.201504123.
- ^ M. Wang, Z. G. Song, H. Jiang, H. Gong. Thermal decomposition of metal methanesulfonates in air. Journal of Thermal Analysis and Calorimetry. 2009-12, 98 (3): 801–806 [2021-12-10]. ISSN 1388-6150. doi:10.1007/s10973-009-0119-z （英語）.
